Áö³ 8¿ù 19ÀϺÎÅÍ 23ÀϱîÁö ¹Ì±¹ American Chemical Society ÇÐȸ°¡ ÀÖ¾ú½À´Ï´Ù.
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Á¦¸ñ: Non-covalent functionalization of single-wall carbon nanotubes by in situ polymerization of micelles
ÃÊ·Ï: We developed a new type of non-covalently (no covalent bonding between the dispersants and SWNTs) functionalized and individually isolated SWNTs (p-SWNT) that are readily re-dispersible (by only 10 minutes of mild vortex mixing) in water even after freeze-drying and stable for months long time period. This was achieved by 1) dispersing SWNTs in water using cationic surfactants,Cetyltrimethylammonium 4-vinylbenzoate (CTVB), which have polymerizable counterions (VB- ions), and 2) permanently fixing the surfactant layer on the SWNTs by polymerizing the counterions. The small-angle neutron scattering, AFM and UV-vis-NIR measurements show that the p-SWNT exists in isolated form, being encapsulated by a cylindrical surfactant monolayer. The water-redispersible isolated p-SWNT may make it possible to prepare highly controlled dispersions of SWNTs in water and allow for further processing in various practical applications. Support from the BAERI program of the ministry of science and technology of Korea.
¹ßÇ¥ºÐ°ú: Surfactant Self-Assembly ½Ã°£, Àå¼Ò, ¹æ¹ý: 8:30 AM-12:05 PM, Tuesday, August 21, 2007 BCEC -- 153B, Oral
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